英语词典化工词典

4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (9CI)

4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (9CI)


  • 中文别名:(R)-二亚甲基-[7,7\'-(1,1\'-螺茚满)]-苯基磷杂环戊烷
  • 英文别名:5-Phenyl-5,6,10,11,12,13-hexahydro-4H-diindeno[7,1-cd:1',7'-ef]ph osphocine;
    (R)-DIMETHYLENE-[7,7'-(1,1'-SPIROINDAN)]-PHENYLPHOSPHOLANE;
    (11AR)-(+)-5,6,10,11,12,13-HEXAHYDRO-5-PHENYL-4H-DIINDENO[7,1-CD:1',7'-EF]PHOSPHOCIN (R)-SITCP;
    (11AR)-(+)-5,6,10,11,12,13-HEXAHYDRO-5-PHENYL-4H-DIINDENO[7,1-CD:1',7'-EF]PHOSPHOCIN, (R)-SITCP 
  • CAS No.:856407-37-9
  • 分子式:C25H23P
  • 精确分子量:354.15400
  • PSA:13.59000
  • InChI:The Key: VAPJMVSYFGSRTG-RUZDIDTESA-N
  • 分子结构式:

MSDS

Section 1: Product Identification
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1’,7’-ef]phosphocin, min. 97% (R)-SITCP
Chemical Name:
CAS Registry Number:856407-37-9
Formula:C25H23P
EINECS Number:none
Chemical Family:organophosphine ligand
Synonym:bis((2,3-dihydro-1H-inden-4-yl)methyl)(phenyl)phosphine; (R)-SITCP
Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound856407-37-9100%no datano data
Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation, eyes
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No
SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.
SECTION 7: Handling and Storage
Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep in a cool, dry,
Handling and Storage:
well-ventilated place.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form:white solid
Molecular Weight:354.42
Melting Point:148-149°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble
SECTION 10: Stability and Reactivity
Stability:moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:prolonged exposure to moisture
Incompatibility:strong oxidizing agents
Decomposition Products:carbon monoxide, carbon dioxide, phosphorus oxides and organic fumes.
SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data
SECTION 12: Ecological Information
Ecological Information:No information available
SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA
SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Not regulated under SARA 313
Second Ingredient:none
SECTION 16 - ADDITIONAL INFORMATION
N/A

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