2-Propenoic acid,3-(2-chloro-6-fluorophenyl)-
- 中文别名：2-氯-6-氟肉桂酸
- 中文释义：2-氯-6-氟肉桂酸;2-氯-6-氟肉桂酸,PREDOMINANTLY TRANS
- 英文别名：2-CHLORO-6-FLUOROCINNAMIC ACID;
2-Chloro-6-fluorocinnamic acid;
2-Chloro-6-fluorocinnamicacid;
2-Chloro-6-fluorocinnamic acid,predominantly trans;
6-Fluor-2-chlor-trans-zimtsaeure;
6-fluoro-2-chloro-trans-cinnamic acid;
RARECHEM BK HW 0069
- CAS No.：392-22-3
- 分子式：C9H6ClFO2
- 分子量：200.6
- 精确分子量：200.00400
- PSA：37.30000
- MDL：MFCD00051582
- InChI：InChI=1/C9H6ClFO2/c10-7-2-1-3-8(11)6(7)4-5-9(12)13/h1-5H,(H,12,13)/b5-4-
- 分子结构式：
物化性质
- 密度：
- 1.42g/cm3
- 熔点：
- 165-169 °C(lit.)
- 沸点：
- 312.8ºC at 760mmHg
- 闪点：
- 143ºC
- 折射率：
- 1.604
- 其它信息：
一、物性数据
性状：灰白色结晶粉末密度（g/mL,25/4℃）：不可用相对蒸汽密度（g/mL,空气=1）：不可用熔点（ºC）：165-169 2-氯-6-氟肉桂酸 安全信息
- 海关代码：
- 2916399090
- WGK_Germany：
- 3
德国有关水污染物质的分类清单 - 危险类别码：
- R36/37/38
- 安全说明：
- S26-S37/39
- 安全标志：
- S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
: - 危险标志：
- Xi: Irritant;
安全信息
- 密度：
- 1.42g/cm3
- 熔点：
- 165-169 °C(lit.)
- 沸点：
- 312.8ºC at 760mmHg
- 闪点：
- 143ºC
- 折射率：
- 1.604
- 其它信息：
一、物性数据
性状：灰白色结晶粉末密度（g/mL,25/4℃）：不可用相对蒸汽密度（g/mL,空气=1）：不可用熔点（ºC）：165-169 2-氯-6-氟肉桂酸 安全信息
- 海关代码：
- 2916399090
- WGK_Germany：
- 3
德国有关水污染物质的分类清单 - 危险类别码：
- R36/37/38
- 安全说明：
- S26-S37/39
- 安全标志：
- S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
: - 危险标志：
- Xi: Irritant;
毒理性
- 毒理学数据：
二、毒理学数据：
急性毒性：不可用。
- 生态数据：
三、生态学数据：
1、其它有害作用：该物质对环境可能有危害，对水体应给予特别注意。
MSDS
| Name: | 2-Chloro-6-fluorocinnamic acid 98% Material Safety Data Sheet |
| Synonym: | |
| CAS: | 392-22-3 |
Section 1 - Chemical Product MSDS Name:2-Chloro-6-fluorocinnamic acid 98% Material Safety Data Sheet
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | content | EINECS# |
| 392-22-3 | 2-Chloro-6-fluorocinnamic acid | 98% | unlisted |
Hazard Symbols: XI
Risk Phrases: 36/37/38
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.
Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 392-22-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Crystalline powder
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 163 - 165 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C9H6ClFO2
Molecular Weight: 200.6
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 392-22-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Chloro-6-fluorocinnamic acid - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 392-22-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 392-22-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 392-22-3 is not listed on the TSCA inventory.
It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
N/A
海关数据
中国海关编码：2916399090
- 概述：
- 2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
- 申报要素：
- 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装
- 摘要/Summary：
- 2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
分子结构与计算化学数据
分子结构数据
1、摩尔折射率：48.59
2、摩尔体积（m3/mol）：141.13、等张比容（90.2K）：375.04、表面张力（dyne/cm）：49.75、极化率（10-24cm3）：19.26
