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1H-Indole-1-carboxylicacid, 2,3-dihydro-2-(hydroxymethyl)-, phenylmethyl ester

1H-Indole-1-carboxylicacid, 2,3-dihydro-2-(hydroxymethyl)-, phenylmethyl ester


  • 中文别名:1-CBZ-2-羟甲基吲哚啉
  • 中文释义:1-CBZ-2-羟甲基吲哚啉;2-(羟基甲基)吲哚啉-1-羧酸苄酯;2,3-二氢-2-(羟甲基)-1H-吲哚-1-羧酸苄酯
  • 英文别名:benzyl 2-(hydroxymethyl)-2,3-dihydroindole-1-carboxylate;
    Benzyl 2-(hydroxymethyl)-1-indolinecarboxylate;
    1-benzyloxycarbonylindoline-2-methanol 
  • CAS No.:135829-04-8
  • 分子式:

    C17H17NO3

  • 分子量:283.32
  • 精确分子量:283.12100
  • PSA:49.77000
  • InChI:InChI=1/C17H17NO3/c19-11-15-10-14-8-4-5-9-16(14)18(15)17(20)21-12-13-6-2-1-3-7-13/h1-9,15,19H,10-12H2
  • 分子结构式:

物化性质

密度:
1.251g/cm3
熔点:
67ºC
沸点:
452.2ºC at 760mmHg
闪点:
227.3ºC
折射率:
1.615
蒸汽压:
5.75E-09mmHg at 25°C

安全信息

密度:
1.251g/cm3
熔点:
67ºC
沸点:
452.2ºC at 760mmHg
闪点:
227.3ºC
折射率:
1.615
蒸汽压:
5.75E-09mmHg at 25°C

MSDS

Name: Benzyl 2-(hydroxymethyl)-1-indolinecarboxylate 95+% Material Safety Data Sheet
Synonym: 2-Hydroxymethyl-2,3-dihydro-indole-1-carboxylic acid benzyl este
CAS: 135829-04-8
Section 1 - Chemical Product   MSDS Name:Benzyl 2-(hydroxymethyl)-1-indolinecarboxylate 95+% Material Safety Data Sheet
Synonym:2-Hydroxymethyl-2,3-dihydro-indole-1-carboxylic acid benzyl este
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
135829-04-8 Benzyl 2-(hydroxymethyl)-1-indolinecar 97% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.
Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 135829-04-8: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: pleasant odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 60 - 62 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C17H17NO3
Molecular Weight: 283.33
Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, acids, acid chlorides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 135829-04-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzyl 2-(hydroxymethyl)-1-indolinecarboxylate - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
 
Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 135829-04-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 135829-04-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 135829-04-8 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据

中国海关编码:2933990090

概述:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
摘要/Summary:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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